Heterocyclic Compounds
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ChemInform Abstract: Preparation, Structure, and Unique Redox Properties of Mono-, Bis-, and Tris(diarylmethylene)-1,3,5-trithianes and Related Compounds.
First published: 31 May 2010
Abstract
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ChemInform Abstract
A number of title compounds like (III)—(V) are prepared. Voltammetric analysis shows that a large structural change and/or transannular bonding are induced during their electrochemical oxidation. Bis- and tris(diarylmethylene)-1,3,5-trithianes undergo easy skeletal rearrangement to 1,2,4-trithiane ring systems upon oxidation.
