Volume 31, Issue 51
Isocyclic Compounds
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ChemInform Abstract: Donor/Acceptor Fulleropyrrolidine Triads.

M. Angeles Herranz

M. Angeles Herranz

Dep. Quim. Org., Fac. Cienc. Quim., Univ. Complutense, E-28040 Madrid, Spain

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Beatriz Illescas

Beatriz Illescas

Dep. Quim. Org., Fac. Cienc. Quim., Univ. Complutense, E-28040 Madrid, Spain

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Nazario Martin

Nazario Martin

Dep. Quim. Org., Fac. Cienc. Quim., Univ. Complutense, E-28040 Madrid, Spain

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Chuping Luo

Chuping Luo

Dep. Quim. Org., Fac. Cienc. Quim., Univ. Complutense, E-28040 Madrid, Spain

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Dirk M. Guldi

Dirk M. Guldi

Dep. Quim. Org., Fac. Cienc. Quim., Univ. Complutense, E-28040 Madrid, Spain

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First published: 31 May 2010

Abstract

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ChemInform Abstract

In the novel title compounds (VI) and (X) a noticeable electronic interaction between the electroactive units is observed. Interestingly, (VIa) and (VIb) show reduction potentials similar to that of C60, whereas (VIc) and (X) show reduction potentials which are cathodically shifted in comparison to parent C60. In (VIc) and (X) intramolecular electron transfer processes occur from TTF or extended TTF to the fullerene singlet excited state, rather than from the ferrocene donor.

chemical structure image

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