ChemInform Abstract: Donor/Acceptor Fulleropyrrolidine Triads.
Abstract
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ChemInform Abstract
In the novel title compounds (VI) and (X) a noticeable electronic interaction between the electroactive units is observed. Interestingly, (VIa) and (VIb) show reduction potentials similar to that of C60, whereas (VIc) and (X) show reduction potentials which are cathodically shifted in comparison to parent C60. In (VIc) and (X) intramolecular electron transfer processes occur from TTF or extended TTF to the fullerene singlet excited state, rather than from the ferrocene donor.