Volume 31, Issue 51
Preparative Organic Chemistry
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ChemInform Abstract: Electrochemical Oxidative Coupling of 1,4-Bis(1,4-dithiafulven-6-yl)benzene Cyclophanes.

Dominique Lorcy

Dominique Lorcy

Lab. Synth. Electrosynth. Org., CNRS, Univ. Rennes, F-35042 Rennes, Fr.

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David Guerin

David Guerin

Lab. Synth. Electrosynth. Org., CNRS, Univ. Rennes, F-35042 Rennes, Fr.

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Kamal Boubekeur

Kamal Boubekeur

Lab. Synth. Electrosynth. Org., CNRS, Univ. Rennes, F-35042 Rennes, Fr.

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Roger Carlier

Roger Carlier

Lab. Synth. Electrosynth. Org., CNRS, Univ. Rennes, F-35042 Rennes, Fr.

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Philippe Hascoat

Philippe Hascoat

Lab. Synth. Electrosynth. Org., CNRS, Univ. Rennes, F-35042 Rennes, Fr.

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Andre Tallec

Andre Tallec

Lab. Synth. Electrosynth. Org., CNRS, Univ. Rennes, F-35042 Rennes, Fr.

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Albert Robert

Albert Robert

Lab. Synth. Electrosynth. Org., CNRS, Univ. Rennes, F-35042 Rennes, Fr.

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First published: 31 May 2010

Abstract

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ChemInform Abstract

Novel bridged bis(dithiafulvenyl)benzenes are synthesized by Wittig—Horner olefinations and the redox behavior of these compounds is studied by cyclic voltammetry. Cyclophanes (IIIa) and (VI) are found to undergo electrochemical oxidative coupling to give cyclooligomers.

chemical structure image

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