Volume 31, Issue 34
Heterocyclic Compounds
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ChemInform Abstract: Regioselective Synthesis of New 5-Ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene Bromides and Rearrangement Reaction Thereof.

Rade Markovic

Rade Markovic

Fac. Chem., Univ. Belgrade, YU-11001 Belgrade, Yugoslavia

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Marija Baranac

Marija Baranac

Fac. Chem., Univ. Belgrade, YU-11001 Belgrade, Yugoslavia

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First published: 03 June 2010

Abstract

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ChemInform Abstract

Careful bromination of the readily prepared thiazolidinones (III) results in regioselective formation of the vinyl bromides (IV)/(V). However, at prolonged reaction times (III) are directly converted to the dienic derivatives (VI)/(VII) without isolation of intermediate bromides.

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