ChemInform Abstract: Regioselective Synthesis of New 5-Ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene Bromides and Rearrangement Reaction Thereof.
Abstract
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ChemInform Abstract
Careful bromination of the readily prepared thiazolidinones (III) results in regioselective formation of the vinyl bromides (IV)/(V). However, at prolonged reaction times (III) are directly converted to the dienic derivatives (VI)/(VII) without isolation of intermediate bromides.