Volume 31, Issue 25
Heterocyclic Compounds
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ChemInform Abstract: Lewis Acid Promoted [4 + 2] Annulation of Allylsilane and Allylgermane with Aldimine; Preparation of Tetrahydroquinolines.

Takahiko Akiyama

Takahiko Akiyama

Dep. Chem., Fac. Sci., Gakushuin Univ., Toshima, Tokyo 171, Japan

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Megumi Suzuki

Megumi Suzuki

Dep. Chem., Fac. Sci., Gakushuin Univ., Toshima, Tokyo 171, Japan

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Hirotaka Kagoshima

Hirotaka Kagoshima

Dep. Chem., Fac. Sci., Gakushuin Univ., Toshima, Tokyo 171, Japan

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First published: 07 June 2010

Abstract

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ChemInform Abstract

The reaction of aldimine derivatives with allylmetals in presence of several Lewis acids leads to [4 + 2] cycloannulation products in moderate to good yields.

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