Volume 31, Issue 25
Preparative Organic Chemistry
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ChemInform Abstract: Synthetic Study on Oximidines: A Concise Synthesis of (Z)-Enamides.

Kouji Kuramochi

Kouji Kuramochi

Dep. Appl. Biol. Chem., Univ. Tokyo, Bunkyo, Tokyo 113, Japan

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Hidenori Watanabe

Hidenori Watanabe

Dep. Appl. Biol. Chem., Univ. Tokyo, Bunkyo, Tokyo 113, Japan

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Takeshi Kitahara

Takeshi Kitahara

Dep. Appl. Biol. Chem., Univ. Tokyo, Bunkyo, Tokyo 113, Japan

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First published: 07 June 2010

Abstract

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ChemInform Abstract

The synthesis of (Z)-enamides is achieved via Curtius rearrangement and addition of organometallics to a (Z)-isocyanate. This method can be applied to the formation of oximidines.

chemical structure image

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