Volume 31, Issue 23
Preparative Organic Chemistry
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ChemInform Abstract: A New Method for Synthesis of Unsymmetrical Ureas Using Electrochemically Prepared Trifluoroethyl Carbamates.

Yoshihiro Matsumura

Yoshihiro Matsumura

Inst. Fundam. Res. Org. Chem., Kyushu Univ., Hakozaki, Fukuoka 812, Japan

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Yuki Satoh

Yuki Satoh

Inst. Fundam. Res. Org. Chem., Kyushu Univ., Hakozaki, Fukuoka 812, Japan

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Osamu Onomura

Osamu Onomura

Inst. Fundam. Res. Org. Chem., Kyushu Univ., Hakozaki, Fukuoka 812, Japan

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Toshihide Maki

Toshihide Maki

Inst. Fundam. Res. Org. Chem., Kyushu Univ., Hakozaki, Fukuoka 812, Japan

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First published: 08 June 2010

Abstract

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ChemInform Abstract

The urethanes (III), easily available by electrochemically induced Hofmann rearrangement of the amides (I), readily react with amines to give good yields of unsymmetrical ureas such as (V) and (VII).

chemical structure image

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