Volume 31, Issue 23
Preparative Organic Chemistry
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ChemInform Abstract: Synthesis of Biaryls Using the Coupling Reaction of Diaryldimethyltins with Copper(II) Nitrate.

Genta Harada

Genta Harada

Dep. Chem., Fac. Sci., Tokyo Metrop. Univ., Hachioji, Tokyo 192-03, Japan

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Masato Yoshida

Masato Yoshida

Dep. Chem., Fac. Sci., Tokyo Metrop. Univ., Hachioji, Tokyo 192-03, Japan

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Masahiko Iyoda

Masahiko Iyoda

Dep. Chem., Fac. Sci., Tokyo Metrop. Univ., Hachioji, Tokyo 192-03, Japan

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First published: 08 June 2010

Abstract

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ChemInform Abstract

The title reaction proceeds smoothly at room temperature to produce the corresponding biaryls (II) and (IV) in good to high yields. The required diaryldialkyltins (I) and (III) are prepared by the reaction of aryllithiums with dichlorodialkyltins.

chemical structure image

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