ChemInform Abstract: Total Synthesis of Both Methyl 4a-Carba-D-arabinofuranosides.
Abstract
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ChemInform Abstract
Based on a ring-closing metathesis of the diene (II) and following stereoselective hydrogenation of the resulting cyclopentene derivative (III) the total synthesis of the α- and β-isomeric title compound (VII) and (IX) is reported.