Volume 31, Issue 16
Natural Products
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ChemInform Abstract: Total Synthesis of Both Methyl 4a-Carba-D-arabinofuranosides.

Christopher S. Callam

Christopher S. Callam

Dep. Chem., Ohio State Univ., Columbus, OH 43210, USA

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Todd L. Lowary

Todd L. Lowary

Dep. Chem., Ohio State Univ., Columbus, OH 43210, USA

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First published: 09 June 2010

Abstract

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ChemInform Abstract

Based on a ring-closing metathesis of the diene (II) and following stereoselective hydrogenation of the resulting cyclopentene derivative (III) the total synthesis of the α- and β-isomeric title compound (VII) and (IX) is reported.

chemical structure image

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