Physical Inorganic Chemistry
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ChemInform Abstract: Crystal Structure of [YbCl2(THF)5]+ [WOCl4(THF)]-.
First published: 09 June 2010
Abstract
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ChemInform Abstract
The title compound is obtained as a byproduct from the reaction of Yb[N(SiMe3)2]3 with WCl6 in THF solution. [YbCl2(thf)5]+ [WOCl4(thf)]- crystallizes in the monoclinic space group P2/c with Z = 2. The structure contains [YbCl2(thf)5]+ cations in which the Yb atom is coordinated in a pentagonal-bipyramidal way with the Cl atoms in the axial positions. Counterion is the well-known [WOCl4(thf)]- ion.
