Volume 31, Issue 12
Organoelement Compounds
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ChemInform Abstract: Synthesis of Functional Bisphosphonates via New Palladium-Catalyzed Bis-hydrophosphorylation Reactions.

Aberdeen Allen Jr.

Aberdeen Allen Jr.

Dep. Chem., Brandeis Univ., Waltham, MA 02254, USA

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David R. Manke

David R. Manke

Dep. Chem., Brandeis Univ., Waltham, MA 02254, USA

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Wenbin Lin

Wenbin Lin

Dep. Chem., Brandeis Univ., Waltham, MA 02254, USA

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First published: 09 June 2010

Abstract

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ChemInform Abstract

The scope and mechanism of the Pd-catalyzed bis-hydrophosphorylation of terminal alkynes is discussed. Dimethyl phosphite fails to give bis-addition products.

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