ChemInform Abstract: Asymmetric Hetero Diels—Alder Reaction Catalyzed by Chiral Cationic Palladium(II) and Platinum(II) Complexes.
Abstract
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ChemInform Abstract
Treatment of nonactivated dienes with aldehydes of type (II) and (XI) in the presence of chiral Pd- and Pt-catalysts results in enantioselective formation of pyran derivatives. Excellent ees are obtained starting from the dienes (I) and (VI).