Volume 31, Issue 12
Preparative Organic Chemistry
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ChemInform Abstract: New and Improved Ligands for Highly Enantioselective Catalytic Diphenylzinc Additions to Aryl Aldehydes.

Wei-Sheng Huang

Wei-Sheng Huang

Dep. Chem., Univ. Va., Charlottesville, VA 22901, USA

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Lin Pu

Lin Pu

Dep. Chem., Univ. Va., Charlottesville, VA 22901, USA

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First published: 09 June 2010

Abstract

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ChemInform Abstract

BINAP-type catalysts substituted by electron-withdrawing fluorine atoms show improved catalytic properties for the asymmetric addition of diphenylzinc to aldehydes. Best results are obtained with ligand (I).

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