Volume 31, Issue 12
Physical Inorganic Chemistry
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ChemInform Abstract: New Ternary Phases LnCu5-xCdx (Ln: Ce, Gd, Tb and Yb) with the AuBe5 Structure Type.

V. V. Pavlyuk

V. V. Pavlyuk

Inorg. Chem. Dep., Ivan Franko State Univ., L′viv 290005, Ukraine

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A. I. Horechyj

A. I. Horechyj

Inorg. Chem. Dep., Ivan Franko State Univ., L′viv 290005, Ukraine

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D. G. Kevorkov

D. G. Kevorkov

Inorg. Chem. Dep., Ivan Franko State Univ., L′viv 290005, Ukraine

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G. S. Dmytriv

G. S. Dmytriv

Inorg. Chem. Dep., Ivan Franko State Univ., L′viv 290005, Ukraine

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O. I. Bodak

O. I. Bodak

Inorg. Chem. Dep., Ivan Franko State Univ., L′viv 290005, Ukraine

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J. J. Koziol

J. J. Koziol

Inorg. Chem. Dep., Ivan Franko State Univ., L′viv 290005, Ukraine

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W. Ciesielski

W. Ciesielski

Inorg. Chem. Dep., Ivan Franko State Univ., L′viv 290005, Ukraine

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J. Kapusniak

J. Kapusniak

Inorg. Chem. Dep., Ivan Franko State Univ., L′viv 290005, Ukraine

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First published: 09 June 2010

Abstract

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ChemInform Abstract

A series of LnCu5-xCdx compounds (Ln: Ce, Gd, Tb and Yb; x = 0.9—3.0) are prepared by arc melting of the elements followed by annealing at 570 K (600 h). The structure of the AuBe5 type compounds are determined by powder XRD (cubic, space group Fequation image3m). Homogeneity ranges and lattice parameters of the Ce, Gd, Tb and Yb phases are given. The Cu and Cd atoms are statistically distributed over two crystallographic sites. No phase transition are observed for the ternary phases.

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