ChemInform Abstract: Quantum-Confined Gallium Nitride in MCM-41.
Abstract
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ChemInform Abstract
GaN is inserted into a microporous matrix, MCM-41, via a simple loading technique using the soluble precursor (N3)3GaNMe3. The practical advantage of the adduct-stabilized triazidogallium compound is that the loading process and the conversion into GaN is possible in a non-aqueous medium and can be followed by IR. The thermolysis of the loaded MCM-41 in flowing NH3 (300 °C, 1 h) gives very pure (e.g. hydrocarbon- and oxygen-free) GaN.