Volume 31, Issue 7
Preparative Organic Chemistry
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ChemInform Abstract: Manganese Tetraazaporphines as Effective Catalysts for the Nuclear Oxidation of Aromatics by Peracetic Acid.

Svetlana V. Barkanova

Svetlana V. Barkanova

Org. Intermed. Dyes Inst., Moscow 103787, Russia

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Elena A. Makarova

Elena A. Makarova

Org. Intermed. Dyes Inst., Moscow 103787, Russia

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Oleg L. Kaliya

Oleg L. Kaliya

Org. Intermed. Dyes Inst., Moscow 103787, Russia

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Eugene A. Luk'yanets

Eugene A. Luk'yanets

Org. Intermed. Dyes Inst., Moscow 103787, Russia

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First published: 10 June 2010

Abstract

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ChemInform Abstract

A new class of catalyst, Mn3+ complexes of tetraazaporphines, is studied. This effective catalyst produces a yield of 60-65% menadione in the oxidation of methylnaphthalene with an extremely high catalyst turnover number (3100).

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