Preparative Organic Chemistry
Full Access
ChemInform Abstract: Ferrocenyl Ligands with Two Phosphanyl Substituents in the α,ε Positions for the Transition Metal Catalyzed Asymmetric Hydrogenation of Functionalized Double Bonds.
First published: 10 June 2010
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract
New chiral ferrocenyl ligands (I) with two phosphane substituents give good to excellent enantioselectivities in the reduction of β-dicarbonyl compounds and various functionalized C=C double bonds. Two opposite configurations of the reduced products are obtained by change of the substituent in the benzylic position of the ligand (I).
