Volume 31, Issue 5
Heterocyclic Compounds
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ChemInform Abstract: Acceleration of Photoinduced Charge Separation in Porphyrin-C60 Dyad with an Acetylene Spacer.

Koji Yamada

Koji Yamada

Inst. Sci. Ind. Res., Osaka Univ., Ibaraki, Osaka 567, Japan

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Hiroshi Imahori

Hiroshi Imahori

Inst. Sci. Ind. Res., Osaka Univ., Ibaraki, Osaka 567, Japan

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Yoshinobu Nishimura

Yoshinobu Nishimura

Inst. Sci. Ind. Res., Osaka Univ., Ibaraki, Osaka 567, Japan

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Iwao Yamazaki

Iwao Yamazaki

Inst. Sci. Ind. Res., Osaka Univ., Ibaraki, Osaka 567, Japan

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Yoshiteru Sakata

Yoshiteru Sakata

Inst. Sci. Ind. Res., Osaka Univ., Ibaraki, Osaka 567, Japan

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First published: 11 June 2010

Abstract

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ChemInform Abstract

The first synthesis and photophysical properties of the title compound, compared with those of a porphyrin-C60 dyad with an amide spacer, are reported. The triple bond in the title compound is found to be a good electron transfer mediator.

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