Volume 31, Issue 5
Isocyclic Compounds
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ChemInform Abstract: Single Electron Transfer Reductive Cleavage of the Aryl—Nitrogen Bond in Phenyl-Substituted Dimethylanilines.

U. Azzena

U. Azzena

Dip. Chim., Univ. Sassari, I-07100 Sassari, Italy

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F. Dessanti

F. Dessanti

Dip. Chim., Univ. Sassari, I-07100 Sassari, Italy

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G. Melloni

G. Melloni

Dip. Chim., Univ. Sassari, I-07100 Sassari, Italy

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L. Pisano

L. Pisano

Dip. Chim., Univ. Sassari, I-07100 Sassari, Italy

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First published: 11 June 2010

Abstract

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ChemInform Abstract

N,N-Dimethylaminobiphenyls [cf. (Ia)] and the related 2,6-diphenylaniline (Ib) are efficiently deaminated by reductive aryl—N bond cleavage with Li metal.

chemical structure image

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