Volume 31, Issue 5
Isocyclic Compounds
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ChemInform Abstract: Trifluoromethyl-Substituted Norbornadiene, Useful Solar Energy Material.

Takabumi Nagai

Takabumi Nagai

MEC Lab., Daikin Ind., Ltd., Tsukuba, Ibaraki 305, Japan

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Ikuko Takahashi

Ikuko Takahashi

MEC Lab., Daikin Ind., Ltd., Tsukuba, Ibaraki 305, Japan

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Miwa Shimada

Miwa Shimada

MEC Lab., Daikin Ind., Ltd., Tsukuba, Ibaraki 305, Japan

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First published: 11 June 2010

Abstract

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ChemInform Abstract

The absorption spectra of title compounds, e. g. (II), synthesized from cyclopentadione (I), are reported. Their photochemical valence isomerization to the corresponding quadricyclanes (III) and the thermal reversion isomerization using PMMA solid films are investigated. Title compounds exhibit an efficient fatigue resistance.

chemical structure image

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