Volume 31, Issue 5
Preparative Organic Chemistry
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ChemInform Abstract: Carboxylates as Pronucleophiles in the Phosphine-Catalyzed γ-Addition Reaction.

Carlos Alvarez-Ibarra

Carlos Alvarez-Ibarra

Dep. Quim. Org., Fac. Quim., Univ. Complutense, E-28040 Madrid, Spain

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Aurelio G. Csaky

Aurelio G. Csaky

Dep. Quim. Org., Fac. Quim., Univ. Complutense, E-28040 Madrid, Spain

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Cristina Gomez de la Oliva

Cristina Gomez de la Oliva

Dep. Quim. Org., Fac. Quim., Univ. Complutense, E-28040 Madrid, Spain

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First published: 11 June 2010

Abstract

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ChemInform Abstract

The Trost reaction is extended to the preparation of functionalized allyl carboxylates, accomplished by intermolecular addition of carboxylates to alkynes bearing electron-withdrawing groups.

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