ChemInform Abstract: Manumycin A: Synthesis of the (+)-Enantiomer and Revision of Stereochemical Assignment.
Abstract
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ChemInform Abstract
The first total synthesis of the unnatural enantiomer (+)-manumycin A (IX) leads to a revision of the published structure (X) of the natural product, isolated from Streptomyces parvulus, to the C-4 epimer.