Isocyclic Compounds
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ChemInform Abstract: The First Metal-Catalyzed Intramolecular [5 + 2] Cycloadditions of Vinylcyclopropanes and Alkenes: Scope, Stereochemistry, and Asymmetric Catalysis.
First published: 19 June 2010
Abstract
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ChemInform Abstract
This novel cycloaddition works well with a wide variety of substrates, and generally proceeds with exceptional diastereoselectivity and in good to excellent yields. In the presence of chiral phosphine ligands enantioselective cycloaddition is possible.
