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ChemInform Abstract: γ-Peptides Forming More Stable Secondary Structures than α-Peptides: Synthesis and Helical NMR-Solution Structure of the γ-Hexapeptide Analogue of H-(Val-Ala-Leu)2-OH.
First published: 20 June 2010
Abstract
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ChemInform Abstract
The title γ-hexapeptide (I) is synthesized by double Arndt—Eistert homologation of the corresponding protected amino acids and conventional peptide-coupling method. NMR measurements reveal that (I) adopts a right-handed helical structure helix.
