Preparative Organic Chemistry
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ChemInform Abstract: Synthesis and Stabilities of the Ga(III) and In(III) Chelates of a New Diaminodithiol Bifunctional Ligand.
First published: 20 June 2010
Abstract
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ChemInform Abstract
A new bifunctional hexadentate ligand B6SS (I) is synthesized. The protonation constants are calculated on the basis of potentiometric pH measurements and compared with the known ligand 6SS (II). The stability constants of the In(III) and Ga(III) complexes of (I) and (II) reveal little influence of the side arm on complexation.
