Volume 29, Issue 31
Preparative Organic Chemistry
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ChemInform Abstract: Chiral Allyl Cations in Cycloadditions to Furan: Synthesis of 2-(1′-Phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-3-one in High Enantiomeric Purity.

C. B. W. STARK

C. B. W. STARK

Inst. Org. Chem., Univ. Hannover, D-30167 Hannover, Germany

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U. EGGERT

U. EGGERT

Inst. Org. Chem., Univ. Hannover, D-30167 Hannover, Germany

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H. M. R. HOFFMANN

H. M. R. HOFFMANN

Inst. Org. Chem., Univ. Hannover, D-30167 Hannover, Germany

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First published: 20 June 2010

Abstract

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ChemInform Abstract

The new diastereo- and enantioselective route to the title compound (III) uses chiral 1-phenylethanol as both a convenient chiral auxiliary and a protecting group.

chemical structure image

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