Volume 29, Issue 11
Physical Inorganic Chemistry
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ChemInform Abstract: YBa(Cu1.10Co0.90)O5, Prepared from YBa2Cu3O7.

G. J. GAINSFORD

G. J. GAINSFORD

N. Z. Inst. Ind. Res. Dev., Ind. Res. Ltd., Lower Hutt, N. Z.

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J. L. TALLON

J. L. TALLON

N. Z. Inst. Ind. Res. Dev., Ind. Res. Ltd., Lower Hutt, N. Z.

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C. T. LIN

C. T. LIN

N. Z. Inst. Ind. Res. Dev., Ind. Res. Ltd., Lower Hutt, N. Z.

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First published: 23 June 2010

Abstract

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ChemInform Abstract

Single crystals of the title compound are prepared by a modified flux method reported recently. The compound crystallizes in the tetragonal space group P4/mmm with Z = 1. The structure is closely related to that of the parent YBa2Cu3O7 compound. The apical O atom in the (Cu,Co)O square pyramid is closer to the Cu,Co site than in the parent compound, while the distance between the basal O atoms and the Ba2+ cations is longer.

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