ChemInform Abstract: Synthesis and NMR-Spectroscopic Investigation of Pyrazolo[1,5-a]pyrimidine Derivatives.
Abstract
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ChemInform Abstract
The reaction of diaminonitropyrazole (I) with unsymmetrical β-dicarbonyls (II) prooceds regioselectively to give the 7-oxo-pyrazolopyrimidines (III). A similar reaction proceeds with the enaminoketones (VI) and (IX). The pyrazolopyrimidines (III), (VIIa), and (X) are used for further reaction with dimethylformamide diethylacetal to produce Schiff bases, which are characterized by NMR.