ChemInform Abstract: (Arene)tricarbonylchromium Complexes in Radical Reactions: Samarium(II) Iodide-Mediated Coupling of Chromium-Complexed Benzaldehyde or Acetophenone with Methyl Acrylate.
Abstract
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ChemInform Abstract
Samarium diiodide mediated coupling of the planar chiral tricarbonylchromium complexes (I) of o-substituted arenecarbonyls with methyl acrylate (II) followed by demetalation provides a convenient access to chiral γ-butyrolactones (IV).