Volume 29, Issue 1
Heterocyclic Compounds
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ChemInform Abstract: (Arene)tricarbonylchromium Complexes in Radical Reactions: Samarium(II) Iodide-Mediated Coupling of Chromium-Complexed Benzaldehyde or Acetophenone with Methyl Acrylate.

N. TANIGUCHI

N. TANIGUCHI

Dep. Chem., Fac. Integr. Arts Sci., Univ. Osaka Prefect., Sakai, Osaka 593, Japan

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M. UEMURA

M. UEMURA

Dep. Chem., Fac. Integr. Arts Sci., Univ. Osaka Prefect., Sakai, Osaka 593, Japan

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First published: 24 June 2010

Abstract

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ChemInform Abstract

Samarium diiodide mediated coupling of the planar chiral tricarbonylchromium complexes (I) of o-substituted arenecarbonyls with methyl acrylate (II) followed by demetalation provides a convenient access to chiral γ-butyrolactones (IV).

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