Organoelement Compounds
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ChemInform Abstract: A Room Temperature Stable 1,3-Diphosphaallyl Radical.
First published: 02 August 2010
Abstract
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ChemInform Abstract
Cyclic voltammetry of the corresponding diphosphirenium salt in CH2Cl2 leads by reduction at -1,6 V to the stable radical (I), which can be isolated as red crystals. It is characterized by mass and ESR spectroscopy as well as ab initio calculations.
