Preparative Organic Chemistry
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ChemInform Abstract: Difluorovinylidene, F2C=C:.
First published: 02 August 2010
Abstract
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ChemInform Abstract
Irradiation of the alkyne (I) with λ = 193 nm in an Ar matrix yields exclusively the title carbene. The IR spectrum agrees with results of novel ab initio calculations. At 35-42 K the carbene adds CO and N2.
