Volume 28, Issue 50
Preparative Organic Chemistry
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ChemInform Abstract: (4 + 4) Photocycloaddition of Methyl 1-Naphthoate to Furan.

T. NOH

T. NOH

Dep. Chem. Educ., Seoul Natl. Univ., Kwanak, Seoul 151-742, S. Korea

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C. KIM

C. KIM

Dep. Chem. Educ., Seoul Natl. Univ., Kwanak, Seoul 151-742, S. Korea

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D. KIM

D. KIM

Dep. Chem. Educ., Seoul Natl. Univ., Kwanak, Seoul 151-742, S. Korea

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First published: 02 August 2010

Abstract

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ChemInform Abstract

The hitherto not described title reaction provides the syn-(2 + 2) cycloadduct (III) as the major product and the endo-(4 + 4) cyclodimer (IV) as well as the cage cyclodimer (V) as side products. The effect of the temperature on the photoreaction is studied and the mechanism is elucidated.

chemical structure image

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