Volume 28, Issue 20
Physical Organic Chemistry
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ChemInform Abstract: The Synthesis of Singlet Ground State Derivatives of Non-Kekule Polynuclear Aromatics.

G. ALLINSON

G. ALLINSON

Sch. Chem., Univ. Leeds, Leeds LS2 9JT, UK

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R. J. BUSHBY

R. J. BUSHBY

Sch. Chem., Univ. Leeds, Leeds LS2 9JT, UK

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M. V. JESUDASON

M. V. JESUDASON

Sch. Chem., Univ. Leeds, Leeds LS2 9JT, UK

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J.-L. PAILLAUD

J.-L. PAILLAUD

Sch. Chem., Univ. Leeds, Leeds LS2 9JT, UK

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N. TAYLOR

N. TAYLOR

Sch. Chem., Univ. Leeds, Leeds LS2 9JT, UK

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First published: 04 August 2010

Abstract

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ChemInform Abstract

Cyclic voltammetry studies show that two-electron reduction of compounds (I)-(III) generates their biradicalic dioxy derivatives which have singlet instead of expected triplet ground states.

chemical structure image

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