Isocyclic Compounds
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ChemInform Abstract: δ-Valerolactam Derivative of C60 from Hetero Diels-Alder Reaction with 1,3-Bis(tert-butyldimethylsilyloxy)-2-aza-1,3-butadiene.
First published: 04 August 2010
Abstract
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ChemInform Abstract
The title diene reacts smoothly with C60 to give the piperidone (III) without by-products. The latter is transformed to lactam (VI) which may be an interesting precursor of C60-based amine and amide compounds via ring-opening.
