Preparative Organic Chemistry
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ChemInform Abstract: Studies on Functionally Substituted Azines. Part 5. Reactions of Azines with Nucleophiles and Hydrogen Chloride.
First published: 04 August 2010
Abstract
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ChemInform Abstract
Oxazolopyrimidinium and -triazinium chlorides (I) in the presence of nucleophiles (II) undergo an O-C bond cleavage of the oxazole ring yielding 2-substituted-ethyl derivatives (III). Oxazolotriazine (IV) behaves similarly towards nucleophiles.
