Volume 27, Issue 23
Isocyclic Compounds
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ChemInform Abstract: Osmium-Catalyzed Cyclopropanation of Olefins.

A. DEMONCEAU

A. DEMONCEAU

Lab. Macromol. Chem. Org. Catal., Univ. Liege, B-4000 Liege, Belg.

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C. A. LEMOINE

C. A. LEMOINE

Lab. Macromol. Chem. Org. Catal., Univ. Liege, B-4000 Liege, Belg.

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A. F. NOELS

A. F. NOELS

Lab. Macromol. Chem. Org. Catal., Univ. Liege, B-4000 Liege, Belg.

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First published: June 4, 1996

Abstract

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ChemInform Abstract

(OsCl2(p-cymene))2 is found to be the most selective catalyst for the cyclopropanation of activated olefines (I) with ethyl diazoacetate (II) .

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