Preparative Organic Chemistry
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ChemInform Abstract: Generation of Functional Diversity via Nitroaldol Condensations of . alpha.-Aminoacid Aldehydes - A New and Stereocontrolled Route to Acyclic 1,3-Diamino-2-alcohols.
First published: June 4, 1996
Abstract
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ChemInform Abstract
The condensation of aldehydes (I) and (IV) with the nitroalkane (II) is effectively promoted by Bu4NF. The corresponding 1,3-diamino-2- alcohol precursors (III) and (V) are obtained diastereoselectively.
