Preparative Organic Chemistry
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ChemInform Abstract: The Reaction of Sulfenate Esters with Acyl Chlorides. Formation of Sulfenyl Chlorides, and Trapping Thereof with Alkenes.
First published: April 30, 1996
Abstract
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ChemInform Abstract
Aryl sulfenates (I) react with acyl chlorides to form carboxylic esters and sulfenyl chlorides. The latter are trapped in situ by olefins such as cyclohexene (III) to yield β-chloro sulfides.
