Volume 27, Issue 18
Physical Organic Chemistry
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ChemInform Abstract: Novel Six- and Eight-Membered Heterocycles. A Trithiadiazaphosphorinane and a Pentathiadiazaphosphocine.

S. E. BOTTLE

S. E. BOTTLE

Sch. Chem., Queensl. Univ. Technol., Brisbane 4001, Australia

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R. C. BOTT

R. C. BOTT

Sch. Chem., Queensl. Univ. Technol., Brisbane 4001, Australia

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G. SMITH

G. SMITH

Sch. Chem., Queensl. Univ. Technol., Brisbane 4001, Australia

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U. D. WERMUTH

U. D. WERMUTH

Sch. Chem., Queensl. Univ. Technol., Brisbane 4001, Australia

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C. H. L. KENNARD

C. H. L. KENNARD

Sch. Chem., Queensl. Univ. Technol., Brisbane 4001, Australia

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First published: April 30, 1996

Abstract

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ChemInform Abstract

Single crystal X-ray structure analysis of the title compounds shows a remarkably symmetrical chair arrangement of (I) with bulky tert-butyl groups and phosphonic O-atom occupying pseudoequatorial positions and two independent but conformationally identical molecules in the asymmetric unit of (II).

chemical structure image

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