Volume 27, Issue 16
Natural Products
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ChemInform Abstract: Enantioselective Syntheses of (-)-Anisomycin and Its Propionate Derivative (3097-B1).

Z. SHI

Z. SHI

Shanghai Inst. Org. Chem., Chin. Acad. Sci., Shanghai 200032, Peop. Rep. China

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G. LIN

G. LIN

Shanghai Inst. Org. Chem., Chin. Acad. Sci., Shanghai 200032, Peop. Rep. China

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First published: April 16, 1996

Abstract

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ChemInform Abstract

The key steps in the facile synthesis of the title compounds (XI) are Sharpless asym. epoxidation of the vinylcarbinol (I) and Sharpless asym. dihydroxylation of the alkene (IV).

chemical structure image

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