Preparative Organic Chemistry
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ChemInform Abstract: Free-Radical Carbonylation Using a Zn(Cu)-Induced Reduction System.
First published: April 16, 1996
Abstract
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ChemInform Abstract
Carbonylation of organic iodides, such as (I) in the presence of Zn/ CuI is studied. The main product is in general the expected aldehyde. By addition of activated alkenes the coupling products are mainly obtained. Intramolecular alkene trapping affords cyclopentanone derivatives.
