Volume 27, Issue 16
Preparative Organic Chemistry
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ChemInform Abstract: Carbocyclization of E,E-1,4-Diphenyl-1,3-butadiene with Dichloroalkanes Mediated by Rieke Metals.

M. S. SELL

M. S. SELL

Dep. Chem., Univ. Nebr., Lincoln, NE 68588-0304, USA

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R. D. RIEKE

R. D. RIEKE

Dep. Chem., Univ. Nebr., Lincoln, NE 68588-0304, USA

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First published: April 16, 1996

Abstract

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ChemInform Abstract

Rieke metal complexes of Ba as well as Sr readily react with diphenylbutadiene (I) to form metallocycles, which undergo highly regio- and stereoselective carbocyclization (→ (III)) upon treatment with dichloroalkanes (II).

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