Volume 27, Issue 11
Natural Products
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ChemInform Abstract: Asymmetric Synthesis of 4-Phenyl-1,5-diazacyclooctan-2-one Using Optically Active Vinyl Sulfoxides.

N. ITOH

N. ITOH

Dep. Chem., Fac. Sci., Tokyo Metrop. Univ., Hachioji, Tokyo 192-03, Japan

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H. MATSUYAMA

H. MATSUYAMA

Dep. Chem., Fac. Sci., Tokyo Metrop. Univ., Hachioji, Tokyo 192-03, Japan

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M. YOSHIDA

M. YOSHIDA

Dep. Chem., Fac. Sci., Tokyo Metrop. Univ., Hachioji, Tokyo 192-03, Japan

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N. KAMIGATA

N. KAMIGATA

Dep. Chem., Fac. Sci., Tokyo Metrop. Univ., Hachioji, Tokyo 192-03, Japan

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M. IYODA

M. IYODA

Dep. Chem., Fac. Sci., Tokyo Metrop. Univ., Hachioji, Tokyo 192-03, Japan

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First published: March 12, 1996

Abstract

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ChemInform Abstract

The (S)-enantiomer of the title compound (V) is prepared stereoselectively and serves as intermediate in the synthesis of (-)- homaline (IX). (R)-(V) and (+)-homaline are also synthesized by this method.

chemical structure image

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