Heterocyclic Compounds
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ChemInform Abstract: Study of the Reactivity of Nitriles Towards Diazomethane: Synthesis and Structural Study of N-Methyl-v-triazoles.
First published: March 12, 1996
Abstract
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ChemInform Abstract
The behavior of nitriles (I) and (VII)-(IX) towards CH2N2 is studied. In the case of (Ia)-(Ie) a reaction is observed which leads, via triazoles (III), to formation of the N-methyl isomers (IV)-(VI). Structural features which influence the results are investigated and discussed in detail.
