Isocyclic Compounds
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ChemInform Abstract: Control of the Diastereoselectivity of the Allylation and Deuteration of 2-Hydroxyalkyl Aryl Sulfoxides.
First published: March 12, 1996
Abstract
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ChemInform Abstract
Whereas the radical allylation of the syn educts proceeds with moderate diastereoselectivity, good levels of selectivity can be observed for the anti analogues (Ia) and (Ib). The configuration at C( 1) can be inverted by silyl-protecting of the OH group (→ cf. ( Ic)).
