Isocyclic Compounds
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ChemInform Abstract: Mild and Efficient N-Oxide Promoted Pauson-Khand Reactions with Ethylene.
First published: March 12, 1996
Abstract
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ChemInform Abstract
The Pauson-Khand cyclization of the cobalt alkyne complexes (I) and ethylene (II) is efficiently promoted by trimethylamine N-oxide. The yields are considerably higher than under the reported optimal thermal conditions. The methodology can also be used for the preparation of the taylorione precursor (V).
