Volume 27, Issue 11
Preparative Organic Chemistry
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ChemInform Abstract: Catalytic Asymmetric Hydroboration with Heterotopic P-N Ligands: Trends in Enantioselectivity with Increased Steric Demand.

J. M. VALK

J. M. VALK

Dyson Perrins Lab., Oxford OX1 3QY, UK

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G. A. WHITLOCK

G. A. WHITLOCK

Dyson Perrins Lab., Oxford OX1 3QY, UK

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T. P. LAYZELL

T. P. LAYZELL

Dyson Perrins Lab., Oxford OX1 3QY, UK

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J. M. BROWN

J. M. BROWN

Dyson Perrins Lab., Oxford OX1 3QY, UK

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First published: March 12, 1996

Abstract

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ChemInform Abstract

Rh-catalyzed hydroboration of alkenes is found to yield (R)- or (S)- products depending on the used ligands forming catalysts of disparate steric environments.

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