ChemInform Abstract: Catalytic Asymmetric Hydroboration with Heterotopic P-N Ligands: Trends in Enantioselectivity with Increased Steric Demand.
Abstract
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ChemInform Abstract
Rh-catalyzed hydroboration of alkenes is found to yield (R)- or (S)- products depending on the used ligands forming catalysts of disparate steric environments.