Volume 26, Issue 19
Natural Products
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ChemInform Abstract: Termite Trail Attractants: New Syntheses of Racemic (E)-α-, (Z)-. alpha.- and β-Bisabolenes.

L. ARGENTI

L. ARGENTI

Dip. Chim. Chim. Ind., Univ. Pisa, I-56126 Pisa, Italy

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F. BELLINA

F. BELLINA

Dip. Chim. Chim. Ind., Univ. Pisa, I-56126 Pisa, Italy

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A. CARPITA

A. CARPITA

Dip. Chim. Chim. Ind., Univ. Pisa, I-56126 Pisa, Italy

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N. DELL'AMICO

N. DELL'AMICO

Dip. Chim. Chim. Ind., Univ. Pisa, I-56126 Pisa, Italy

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R. ROSSI

R. ROSSI

Dip. Chim. Chim. Ind., Univ. Pisa, I-56126 Pisa, Italy

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First published: May 9, 1995

Abstract

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ChemInform Abstract

The synthesis of the title compounds (IX), (XV) and (XIX) is described. The key steps are the palladium catalyzed cross-coupling reaction of the stannane (VII), the cuprate mediated coupling of the bromide (XIII) and the zirconium promoted methylenation of the ketone (XVII).

chemical structure image

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