Volume 26, Issue 9
Organoelement Compounds
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ChemInform Abstract: Efficient Synthesis of Substituted 2-Diethylphosphonylbuta-1,3-dienes.

H. AL-BADRI

H. AL-BADRI

Lab. Comp. Organophos., 76131 Mont-Saint-Aignan, Fr.

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E. ABOUT-JAUDET

E. ABOUT-JAUDET

Lab. Comp. Organophos., 76131 Mont-Saint-Aignan, Fr.

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N. COLLIGNON

N. COLLIGNON

Lab. Comp. Organophos., 76131 Mont-Saint-Aignan, Fr.

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First published: February 28, 1995

Abstract

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ChemInform Abstract

The phosphonylbutadienes (V) and (VI) which are difficult to prepare by any other methods are synthesized in two steps by reaction of the lithiated phosphonates (I) with various aromatic or aliphatic aldehydes (II) followed by a stereospecific conversion of the resulting alcohol (III) into the dienes (V) and (VI).

chemical structure image

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