Volume 26, Issue 9
Heterocyclic Compounds
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ChemInform Abstract: A Straightforward Diasteroselective Synthesis of trans-Linalyl Oxide by an Intramolecular SN2′ Reaction.

M.-A. GARCIA

M.-A. GARCIA

Lab. Synth. Org. Select., Ass. CNR, Fac. Sci. Luminy, 13288 Marseille, Fr.

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A. MEOU

A. MEOU

Lab. Synth. Org. Select., Ass. CNR, Fac. Sci. Luminy, 13288 Marseille, Fr.

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P. BRUN

P. BRUN

Lab. Synth. Org. Select., Ass. CNR, Fac. Sci. Luminy, 13288 Marseille, Fr.

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First published: February 28, 1995

Abstract

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ChemInform Abstract

In the diastereoselective cyclization of the monoprotected triols (I) and (IV) to give trans-linalyl oxide (II) the best diastereoselectivities are found when zinc halides are used as Lewic acids.

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